Abstract
reagents1a,breactwith1,2,3-indantrione(2) togivet hedimeric adducts3aand3b,respectively.Moreover,2reactswithtert-butyldiethyl-phosphonoacetate(1c) yielding thee thyleniccompound4. Ontheotherhand,2 reactswith1dtoyield the phosphonateadduct5. Mechan ismsac counting forthe formation of thenewprod uctsarediscusseda ndthepr obablest ructuresofthe
products are presented based on compatible analytical and spectral data.
References
Boulos, L.S.; Abd El-Rahman, N.M.Phosphorus, Sulfur, and Silicon,1991,62, 163.
Boulos, L.S.; Abd El-Rahman, N.M.Phosphorus, Sulfur, and Silicon,1992,68, 241.
Boulos, L.S.; Arsanious M.H.N.Phosphorus, Sulfur, and Silicon,1994,89, 185.
Silverstein, R.N; Bassler, G.C.Spectroscopic Identification of Organic Compounds, 2nded, Wiley:New York,1967, p. 145.
Bellamy, L.J.The Infrared Spectra of Complex Molecules, John Wiley: New York,1964,p. 311.
Ramirez, F.; Madan, O.P.; Heller,S.R.J. Am. Chem. Soc.,1956,87, 713.
Ramirez, F.; Madan, O.P.; Heller, S.R.Tetrahedron Lett.,1965,201.
Crutchfield, M.M.; Dungan, C.H.; Letcher, H.J.; Merk, V.; van Wazer, J.R.Topics in Phosphorus Chemistry, Grayson, M.; Griffith, E.J., eds. Interscience Publishers: New York1967,Vol. 5, pp.
227-447.
Nishiwaki, T.Tetrahedron,1966,22, 711.

This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
Copyright (c) 2024 Food Additives and Contaminants